Publication Type:Journal Article
Source:Journal of Geophysical Research: Atmospheres, Volume 118, Issue 13, p.7379 - 7388 (2013)
Keywords:HCFC‒22, inversion, Troposphere: composition and chemistry
HCFC‒22 (CHClF2, chlorodifluoromethane) is an ozone‒depleting substance, the consumption of which is controlled under the Montreal Protocol. Within a Bayesian inversion framework, we use measurements of HCFC‒22 atmospheric concentrations to constrain estimates of HCFC‒22 emissions, at the grid point 3.75°×2.5° and 8 day resolution, from January 1995 to December 2010. Starting from a new gridded bottom‒up inventory which is then optimized, our method shows continuously rising global emissions, from 182±11 Gg in 1995 to the maximum of 410±9 Gg in 2009. This is mainly due to an increase of emissions in developing regions, particularly in Eastern Asia, and occurs despite the current phase‒out in developed countries. The high temporal resolution of our inversion (8 day) allows to reveal some of the emission seasonality, the global posterior sources ranging from 25 Gg/month in November to 42 Gg/month in July, for example, in 2010.